采煤沉陷区浅层地下水中的营养盐时空分布
2015-11-26范廷玉王月越严家平王顺李国瑞陈威
范廷玉 王月越 严家平 王顺 李国瑞 陈威



摘要:以淮南潘一、潘三矿采煤沉陷区(开放型沉陷区)和后湖采煤沉陷区(封闭型沉陷区)为研究区域,通过对沉陷区浅层地下水中氮、磷等营养盐指标的监测,研究了两种类型采煤沉陷积水区浅层地下水中营养元素的时空分布特征,采用相关性分析初步研究了不同类型沉陷区营养盐的迁移特征,同时分析了营养盐的限制性组成。结果表明,NH3-N年内时间差异性较小,整体呈开放型浅层地下水(KD)>封闭型浅层地下水(FD);NO2--N、NO3--N和凯氏氮年内空间差异性较小,时间差异性较大,丰水期低于平枯水期;总氮年内时空差异性均较小,基本呈FD>KD。PO43-和总磷年内时间差异性较大,溶解性总磷年内时空差异性较小。开放型沉陷区浅层地下水内各营养盐指标的相关性更强,封闭型沉陷区浅层地下水中磷的污染风险更大。
关键词:采煤沉陷区;浅层地下水;营养盐
中图分类号:X824 文献标识码:A 文章编号:0439-8114(2015)21-5272-05
DOI:10.14088/j.cnki.issn0439-8114.2015.21.017
Nutrients Distribution in Shallow Underground Water of Coal Mine Subsidence Area
FAN Ting-yu,WANG Yue-yue,YAN Jia-ping,WANG Shun,LI Guo-rui,CHEN Wei
(School of Earth and Environment, Anhui University of Science and Technology, Huainan, 232001, Anhui, China)
Abstract:To find out temporal and spatial distribution characteristics of nutrients such as nitrogen, phosphrous, etc in the shallow groundwater of different types of coal mine subsidence area, open (Pan1and Pan3) and closed(Houhu) subsidence area in Huainan were selected and nine sets of monitoring data from November 2012 to September 2013 were analyzed. Correlation analysis revealed different response relationship and migration characteristics of nitrogen and phosphorus in the same water body. Compositions of nitrogen and phosphorus in two types of water body were analyzed based on their ratios of various forms. Results showed that the temporal difference of NH3-N was small in both water bodies, though it was larger in KD(open shallow groundwater)than in FD (closed shallow groundwater) in general. On average, the temporal differences of NO2--N、NO3--N and KN were big, and the spatial differences were small, while both were lower during wet season than in dry or normal reason. The temporal and spatial distribution difference of total nitrogen(TN) were both little and presented FD>KD. The spatial difference of PO43- and TP was large, while the temporal and spatial difference of TSP was small. The nutrient elements were more related to each other in open subsidence area than in closed subsidence area as to the compositions of nitrogen and phosphorus, certain differences existed in the two water bodies and phosphorus pollution risk was greater in shallow underground water of closed coal mine subsidence area.
Key words:coal mine subsidence area; shallow groundwater; nutrient
煤炭是中国乃至当今世界的主要基础能源之一,中国约96%的煤炭为井工开采,4%为露天开采[1]。井工开采万吨原煤造成的沉陷地约0.20~0.33 hm2[2]。华北平原煤炭储量占全国保有储量的49.25%,煤炭开采量伴随着需求量的急剧升高而大幅度增加,进而引起大面积地表沉陷[3,4],为地表水资源蓄积的形成创造了良好条件。淮南矿区自20世纪50年代规模型开采以来,至今已有60多年。在大气降水、河流汇入以及较高的新生界含水层地下水位等作用下,形成了不同格局的稳沉或非稳沉地表沉陷积水区,改变了地形微地貌单元,使得在一定条件下的区域水文地质条件、水文循环模式不断发生变化,并引起一定区域范围内地下水的补、径、排条件发生变化[5,6]。因此,……
