茶叶高氯酸盐污染及分析技术
2019-08-21邓家军潘华张富生张莉曹芳张志芳陈俊松
邓家军,潘华,张富生,张莉,曹芳,张志芳,陈俊松
茶叶高氯酸盐污染及分析技术
邓家军1,2,潘华1,2,张富生1,2,张莉1,2,曹芳1,2,张志芳1,2,陈俊松3
1. 江西省农产品质量安全检测中心,江西 南昌 330046;2. 农业部农产品质量安全风险评估实验室(南昌),江西 南昌 330046;3. 九江市农产品质量安全监测中心,江西 九江 332000
高氯酸盐是茶叶中的一种新型污染物,对茶叶产品质量安全、人体健康和对外贸易构成了潜在风险,已引起了国内外越来越多的关注。本文综述了茶叶中高氯酸盐的来源及污染现状,介绍了茶叶中高氯酸盐的分析技术,以期为开展高氯酸盐环境化学行为、农产品质量安全、人体健康风险及其相关安全标准等方面的研制提供借鉴。
茶叶;高氯酸盐;污染;分析技术


1.1 环境中污染来源
1.1.1 自然来源

1.1.2 人为生产



1.2 环境中污染状况

2 茶叶中的污染
2.1 茶叶中污染现状

2.2 茶叶中污染来源
3.1 IC法

3.2 IC-MS/MS法


表1 文献报道过的方法比较
注:NR:未见报道
Note: NR: not reported
3.3 LC-MS/MS法
4 结语
[1] 梅宇. 2014年中国茶叶产销报告及2015年形势预测[J]. 茶世界, 2015(6): 50-59.
[2] 梅宇, 王智超. 2016全国春茶产销形势分析报告[J]. 茶世界, 2016(6): 40-49.
[3] 梅宇. 2016年中国茶业经济形势简报[J]. 茶世界, 2017(2): 14-18.
[4] 梅宇, 王智超, 林璇. 2017年全国春茶产销形势分析报告[J]. 茶世界, 2017(5): 14-22.
[5] 陈宗懋. 我国茶产业质量安全和环境安全问题研究[J]. 农产品质量与安全, 2011(3): 5-7.
[6] 韩文炎, 鲁成银, 刘新. 我国茶叶在种植环节的质量安全问题及对策[J]. 食品科学技术学报, 2014, 32(2): 12-15.
[7] 刘新, 张颖彬, 潘蓉, 等. 我国茶叶加工过程的质量安全问题及对策[J]. 食品科学技术学报, 2014, 32(2): 16-19.
[8] European Commission. Statement as regards the presence ofperchlorate in food endorsed by the Standing Committee on Plants, Animals, Food and Feed on 10 March 2015, updated on 23 June 2015 [EB/OL]. (2015-06-23)[2018-09-10]. https://ec.europa.eu/food/sites/food/files/safety/docs/cs_con taminants_catalogue_perchlorate_statement_food_update_en.pdf .
[9] Leung A M, Pearce E N, Braverman L E. Perchlorate, iodine and the thyroid [J]. Best Practice & Research Clinical Endocrinology & Metabolism, 2010, 24(1): 133-141.
[10] Blount B C, Pirkle J L, Osterloh J D, et al.Urinary perchlorate and thyroid hormone levels in adolescent and adult men and women living in the United States [J]. Environmental Health Perspectives, 2006, 114(12): 1865-1871.
[11] EFSA Panel on Contaminants in the Food Chain (CONTAM). Scientific opinion on the risks to public health related to the presence of perchlorate in food, in particular fruits and vegetables [J]. EFSA Journal, 2014, 12(10), 3869. https://doi.org/10.2903/j.efsa.2014.3869.
[12] Acevedo-Barrios R, Sabater-Marco C, Olivero-Verbel J. Ecotoxicological assessment of perchlorate usingandassays [J]. Environmental Science & Pollution Research International, 2018, 25(14): 13697-13708.
[13] USEPA. Announcement of the Drinking Water Contaminant Candidate List. Notice [J]. Federal Regist, 1998, 63(40): 10273-10287.
[14] Kannan K, Praamsma M L, Oldi J F, et al. Occurrence of perchlorate in drinking water, groundwater, surface water and human saliva from India [J]. Chemosphere, 2009, 76(1): 22-26.
[15] Kumarathilaka P, Oze C, Vithanage M. Perchlorate mobilization of metals in serpentine soils [J]. Applied Geochemistry, 2016, 74: 203-209
[16] Kumarathilaka P, Oze C, Indraratne S P, et al. Perchlorate as an emerging contaminant in soil, water and food[J]. Chemosphere, 2016, 150: 667-677.
[17] Calderón R, Godoy F, Escudey M, et al. A review of perchlorate (ClO4-) occurrence in fruits and vegetables [J]. Environmental Monitoring & Assessment, 2017, 189(2): 82. https://doi.org/10.1007/s10661-017-5793-x.
[18] Lee S Y, Mccarthy A M, Stohl H E, et al. Urinary iodine, perchlorate, and thiocyanate concentrations in U.S. lactating women [J]. Thyroid, 2017, 27(12): 1574-1581.
[19] Zhang T, Wu Q, Sun H W, et al. Perchlorate and iodide in whole blood samples from infants, children, and adults in Nanchang, China [J]. Environmental Science & Technology, 2010, 44(18): 6947-6953.
[20] Qin X, Zhang T, Gan Z, et al. Spatial distribution of perchlorate, iodide and thiocyanate in the aquatic environment of Tianjin, China [J]. Environmental source analysis, Chemosphere, 2014, 111: 201-208.
[21] Wan Y, Wu Q, Abualnaja K O, et al. Occurrence of perchlorate in indoor dust from the United States and eleven other countries: Implications for human exposure [J]. Environment International, 2015, 75: 166-171.
[22] Jackson W A, Böhlke J K, Gu B, et al. Isotopic composition and origin of indigenous natural perchlorate an co-occurring nitrate in the Southwestern United States [J]. Environmental Science & Technology, 2010, 44(13): 4869-4876.
[23] Rao B, Anderson T A, Redder A, et al. Perchlorate formation by ozone oxidation of aqueous chlorine/oxy-chlorine species: Role of ClxOyradicals [J]. Environmental Science & Technology, 2010, 44(8): 2961-2967.
[24] Rao B, Estrada N, McGee S, et al. Perchlorate production by photodecomposition of aqueous chlorine solutions [J]. Environmental Science & Technology, 2012, 46(21): 11635-11643
[25] Kang N, Jackson W A, Dasgupta P K, et al. Perchlorate production by ozone oxidation of chloride in aqueous and dry systems [J]. Science of the Total Environment, 2008, 405(1/3): 301-309.
[26] Jiang S, Li, Y S, Sun B. Determination of trace level of perchlorate in Antarctic snow and ice by ion chromatography coupled with tandem mass spectrometry using an automated sample on-line preconcentration method [J]. Chinese Chemical Letters, 2013, 24(4): 311-314.
[27] Duncan P B, Morrison R D, Vavricka E. Forensic identification of anthropogenic and naturally occurring sources of perchlorate [J]. Environmental Forensics, 2005, 6(2): 205-215.
[28] Michalski J, Böhlke J K, Thiemens M. Long-term atmospheric deposition as the source of nitrate and other salts in the Atacama Desert, Chile: New evidence from mass-independent oxygen isotopic compositions [J]. Geochimica et Cosmochimica Acta, 2004, 68(20): 4023-4038.
[29] Wu C, Sullivan K, Chowdhury S, et al. Encapsulation of perchlorate salts within metal oxides for application as nanoenergetic oxidizers [J]. Advanced Functional Materials, 2012, 22(1): 78-85.
[30] Wilkin R T, Fine D D, Burnett N G. Perchlorate behavior in a municipal lake following fireworks displays [J]. Environmental Science & Technology, 2007, 41(11): 3966-3971.
[31] Shi Y L, Zhang N, Gao J M, et al. Effect of fireworks display on perchlorate in air aerosols during the Spring Festival [J]. Atmospheric Environment, 2011, 45(6): 1323-1327.
[32] Isobe T, Ogawa S P, Sugimoto R, et al. Perchlorate contamination of groundwater from fireworks manufacturing area in South India [J]. Environmental Monitoring and Assessment, 2013, 185(7): 5627-5637.
[33] Urbansky E T, Brown S K, Magnuson M L, et al. Perchlorate levels in samples of sodium nitrate fertilizer derived from Chilean caliche [J]. Environ Pollut, 2001, 112(3): 299-302
[34] Susarla S, Collette T W, Garrison A W, et al. Perchlorate identification in fertilizers [J]. Environmental Science & Technology, 1999, 33(19): 3469-3472.
[35] Massachusetts Department of Environmental Protection. The occurrence and sources of perchlorate in Massachusetts—Draft report [EB/OL]. (2006-04)[2018-09-10].http://www.mass.gov/eea/docs/dep/cleanup/sites/percsour.pdf.
[36] Barron L, Nesterenko P N, Paull B. Rapid on-line preconcentration and suppressed micro-bore ion chromatography of part per trillion levels of perchlorate in rainwater [J]. Anal Chim Acta, 2006, 567(1): 127-134.
[37] Furdui V, Tomassini F. Trends and sources of perchlorate in Arctic snow [J]. Environmental Science & Technology, 2010, 44(2): 588-592.
[38] Parker D R, Seyfferth A L, Reese B K. Perchlorate in groundwater: a synoptic survey of “pristine” sites in the coterminous United States [J]. Environmental Science & Technology, 2008, 42(5): 1465-1471.
[39] Ji G L, Kong X L. Adsorption of chloride, nitrate and perchlorate by variable charge soils [J]. Pedosphere. 1992, 2(4): 317-326.
[40] Urbansky E T, Brown S K. Perchlorate retention and mobility in soils [J]. Journal of Environmental Monitoring, 2003, 5(3): 455-462.
[41] Tipton D K, Rolston D E, Scow K M. Transport and biodegradation of perchlorate in soils [J]. Journal of Environmental Quality 2003, 32(1): 40-46.
[42] Gan Z, Sun H, Wang R, et al. Occurrence and exposure evaluation of perchlorate in outdoor dust and soil in mainland China [J]. Science of the Total Environment, 2014, 470/471: 99-106.
[43] Ye L, You H, Yao J, et al. Seasonal variation and factors influencing perchlorate in water, snow, soil and corns in Northeastern China [J]. Chemosphere, 2013, 90(10): 2493-2498.
[44] Qin X, Zhang T, Gan Z, et al. Spatial distribution of perchlorate, iodide and thiocyanate in the aquatic environment of Tianjin, China: Environmental source analysis [J]. Chemosphere, 2014, 111: 201-208.
[45] Wu Q, Zhang T, Sun H, et al. Perchlorate in tap water, groundwater, surface waters, and bottled water from China and its association with other inorganic anions and with disinfection byproducts [J]. Archives of Environmental Contamination and Toxicology, 2010, 58(3): 543-550.
[46] Smith P N, Yu L, McMurry S T et al. Perchlorate in water, soil, vegetation, and rodents collected from the Las Vegas Wash, Nevada, USA [J]. Environmental Pollution, 2004, 132(1): 121-127.
[47] Kim D H, Yoon Y, Baek K, et al. Occurrence of perchlorate in rice from different areas in the Republic of Korea [J]. Environmental Science and Pollution Research, 2014, 21(2): 1251-1257.
[48] Seyfferth A L, Sturchio N C, Parker D R. Is perchlorate metabolized or re-translocated within lettuce leaves? A stable isotope approach [J]. Environmental Science & Technology, 2008, 42(24): 9437-9442.
[49] Seyfferth A L, Henderson M K, Parker D R. Effects of common soil anions and pH on the uptake and accumulation of perchlorate in lettuce [J]. Plant Soil, 2008, 302(1/2): 139-148.
[50] Yu L, Canas J E, Cobb G P, et al. Uptake of perchlorate in terrestrial plants [J]. Ecotoxicology and Environmental Safety, 2004, 58(1): 44-49.
[51] Yifru D D, Nzengung V A. Uptake of perchlorate by vegetation growing at field sites in arid and subhumid climates [J]. Remediation Journal, 2007, 17(4): 53-68.
[52] Sanchez C A, Crump K S, Krieger R I, et al. Perchlorate and nitrate in leafy vegetables of North America [J]. Environmental Science & Technology, 2005, 39(24): 9391-9397.
[53] Yang M, Her N. Perchlorate in soybean sprouts (L. Merr.), water dropwort (DC), and lotus (Gaertn.) root in South Korea [J]. Journal of Agricultural and Food Chemistry, 2011, 59(13): 7490-7495.
[54] 陈桂葵, 骆……
