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2A50铝合金在含有较低氯离子浓度溶液中的腐蚀性能研究

2019-08-07冯一可

科技视界 2019年17期

冯一可

【摘 要】在含有卤素离子的溶液中2A50铝合金易发生腐蚀,具有明显的局部腐蚀倾向。在某些特殊用途的、仅含有较低水平氯离子浓度(不高于50mg/L)的溶液中,对2A50铝合金的耐晶间腐蚀和应力腐蚀的能力进行了考察。通过试验可发现,即使是在含有较低Cl-浓度的溶液中,2A50铝合金依然表现出明显的晶间腐蚀和应力腐蚀倾向。在短时间内腐蚀形貌以点蚀和晶间腐蚀为主,但随着时间的延长和加载应力的逐步增大,2A50铝合金开始出现典型的应力腐蚀开裂形貌。

【关键字】铝合金;氯离子浓度;晶间腐蚀;应力腐蚀

中图分类号: TG172.3文献标识码: A文章编号: 2095-2457(2019)17-0104-003

DOI:10.19694/j.cnki.issn2095-2457.2019.17.049

Research of Corrosion Resistance for Aluminum Alloy 2A50 in Solution with Lower Concentration of Chloride Ion

FENG Yi-ke

(Research Institute of Physical and Chemical Engineering of Nuclear Industry, Tianjin 300180, China)

【Abstract】Aluminum alloy has local corrosion tendency which corrosion behavior is easily found in solution with halide ions. This kind of aluminum alloy is studied in this paper to research its corrosion resistance, such as intergranular corrosion and stress corrosion in some special-purpose solution with lower concentration of Cl-. And obvious corrosion tendency of intergranular corrosion and stress corrosion of aluminum alloy 2A50 is found in solution even with very lower concentration of Cl-. In short cycles pitting and intergranular corrosion are easily found while the failure style mainly is stress corrosion cracking with time going and external stress increasing. Keywords: equipment failure; intergranular corrosion; stress corrosion.

【Key words】Aluminum alloy; The concentration of Cl-; Intergranular corrosion; Stress corrosion

2A50合金是高强度锻铝,在热态下具有很高的可塑性,易于锻造、冲压,可以热处理强化,在淬火及人工时效后的强度与硬铝相似,机加工性能较好,但有挤压效应,故纵向和横向性能有所差异,耐全面腐蚀性能较好,但有局部腐蚀的倾向。本次研究针对某些特殊的使用条件,对2A50铝合金处于Cl-浓度较低水平的溶液时所表现出的耐晶间腐蚀和应力腐蚀的性能予以考察。

1 试验方案

1.1 试验溶液的配置

在试验过程中,通过蒸馏水配置了以下3种含有Cl-的溶液,分别为:Cl-浓度约0.5mg/L、5mg/L和50mg/L。

1.2 试样的选取

试样取某厂加工生产的2A50铝合金模锻件。

1.3 试样的制备

晶间腐蚀试验的试样采用尺寸为40mm×25mm×10mm的试块,在样品的制备上比较简单。

应力腐蚀试验的试样在制备上按照GB/T 22640-2008《铝合金加工产品的环形试样应力腐蚀试验方法》规定的方法在2A50铝合金模锻件上取C型环样。……

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