Hai Zhou, Hao Wang,†, and Liming Ding

1School of Microelectronics, Hubei Key Laboratory of Ferroelectric and Dielectric Materials and Devices, Hubei University, Wuhan 430062,China

2Center for Excellence in Nanoscience (CAS), Key Laboratory of Nanosystem and Hierarchical Fabrication (CAS), National Center for Nanoscience and Technology, Beijing 100190, China

Metal halide perovskite nanowires (PNWs) have attracted great attention not only because they have some advantages, such as long carrier diffusion length, high absorption coefficient, and low defect state density, etc.[1-3], but also because the nanowires perform efficient charge carrier transporting and possess large surface-to-volume ratio, driving PNWs to be applied in solar cells[4,5], lasers[6], and photodetectors(PDs)[7,8]. Up to now, the high-performance PNW devices are all based on single nanowire or nanowire arrays[7,8]. The complexity of the preparation process, the poor reproducibility and the high cost block the large-area fabrication and commercial application.

Owing to the easy fabrication, solution-processed perovskite nanowire networks (PNNs) show the potential in commercialization compared with single nanowire or nanowire arrays counterparts[4,9,10]. For example, Singhet al. reported MAPbI3PNN-based solar cells[4], indicating that the partiallygrown PNNs in the active layer yielded a power conversion efficiency (PCE) of 18.7%. Besides, a PNN PD was developed by Asuoet al.viasolution processing under ambient conditions[10]. By adding thiocyanate, the PDs showed a good performance with 50μs response time (Fig. 1(a)), 0.23 A/W responsivity and specific detectivity of 7.1 × 1011Jones at 490 nm under 2 V bias. Despite these progresses in PNN-based devices, the micro-interfaces among PNNs increased exciton transport barrier and affected the charge generation and transport, limiting the enhancement of device performance.

Denget al.[11]reported flexible and transparent PNN PD made on poly(ethylene terephthalate) (PET) by regulating perovskite crystallization (Fig. 1(b)). The trade-off between device performance and transparency was studied. The device offered switching ratio, detectivity, and equivalent dark current derived shot noise of 300, 1.02 × 1012Jones, and 4.73 × 10-15A/Hz1/2, respectively. Furthermore, the perovskite network PD arrays made on PET substrates presented good flexibility. The perovskite networks protected with hydrophobic polymers improved device stability by improving surface passivation and moisture isolation.

Fanget al.[12]demonstrated mixed-dimensional van der Waals (vdW) heterostructures between one dimensional (1D)CsPbBr3PNNs and two-dimensional (2D) transition metal dichalcogenides (TMDCs). CsPbBr3/MoS2and CsPbBr3/WSe2were type-I and type-II heterostructures (Fig. 1(c)), respectively. Charge transfer from CsPbBr3to MoS2showed an efficiency of 71%, while holes transferred from CsPbBr3to WSe2with an efficiency of 70%. The excellent charge transfer in 1D/2D perovskite-TMDC heterostructures enables potential application in optoelectronic devices.

For boosting device performance and stability, Wuet al.[13]demonstrated a welding strategy to enhance the crystallinity of MAPbI3PNNs and the radial transport of charge carriers, resulting in better device performance and stability (Fig. 1(d)).The PNN PDs delivered an on/off ratio and detectivity of 2.8 × 104and 4.16 × 1012Jones, respectively, similar to the performance of single-NW or NW array PDs. The devices presented good stability in air (humidity 55%-65%). The flexible PNN PDs could make 1000 bending cycles with no performance deterioration.

Except PNN devices with the MSM structure, a selfpowered CsPbBr3PNN PD with a vertical structure was also reported (Fig. 1(e))[14]. Before coating the hole-transport layer,poly(methyl methacrylate) was coated onto perovskite NW film to fill the voids, passivating surface defects and reducing dark current. The devices offered a dark current density of 4.0 nA/cm2and a photocurrent density of 22.9 mA/cm2under a laser illumination (473 nm, 641 mW/cm2), yielding a high linear dynamic range of 135 dB. The devices also presented >106on/off ratio, 0.3 A/W responsivity, and 1013Jones detectivity at 0 V.

Lead toxicity retards the commercialization of lead perovskite-based devices. Tanget al.[15]used a two-step solution method for making tin-based PNNs PDs. The dark current of CsPbxSn1-x(BryI1-y)3PNN PDs increased with the increase of tin content (Fig. 1(f)). The lowest dark current (0.672 nA at 1 V) was obtained. The best device delivered a linear dynamic range of 120 dB, a rise/fall time of 4.25/4.82 ms, and a detectivity of 2 × 1010Jones. Moreover, Sn-based PNN devices could keep performance after being stored in air for 30 days.

The above reports clearly present the structures and the performance for PNN-based photodetectors. However, deep understanding on the performance enhancement is still required. More efforts should be put onto new materials development and device engineering.

Acknowledgements

This work was supported by the National Natural Science Foundation of China (11874143, 51972101) and the Natural Science Foundation of Hubei Province (2019CFB508). L.Ding thanks the National Key Research and Development Program of China (2017YFA0206600) and the National Natural Science Foundation of China (51773045, 21772030, 51922032,21961160720) for financial support.

Fig. 1. (Color online) (a) SEM image for PNNs and the response time of the PDs. Reproduced with permission[10], Copyright 2018, Elsevier. (b) The schematic of a PD (top) and photograph of network PD arrays (bottom). Reprinted with permission[11], Copyright 2015, American Chemical Society. (c) Schematic of charge transfer pathways at the interface of PNNs/TMDC heterostructures upon 405 nm laser photoexcitation; side view of PNNs/TMDC heterostructure interface. Reprinted with permission[12], Copyright 2018, American Chemical Society. (d) Enhancing device performance by using the welding strategy. Reprinted with permission[13], Copyright 2020, American Chemical Society. (e) Cross-sectional SEM image for perovskite NW PD. The scale bar is 500 nm. Reprinted with permission[15], Copyright 2018, Elsevier. (f) Absorption spectra for Br-rich perovskite NWs with different Sn2+ concentrations. Reproduced with permission[14], Copyright 2020, American Chemical Society.