JOURNAL OF FUNCTIONAL POLYMERS

VoI.29 No.1 March 2016 CONTENTS

SpeciaI Reviews

Research Progress in FunctionaI MateriaIs Based on PoIyoxometaIate-PoIymer Hybrids

YANG Hai-kuan,WU Han,WANG Wei

Journal of Functional Polymers,2016,29（1）：1-19.

Advanced functional materials based on polyoxometalate-polymer hybrids with polymer processability and the functions of polyoxometalate（POM）clusters have important application prospect.

Advance in ChiraIity of AchiraI Substance Induced by ChiraI SoIvent

ZHAO Yin,YIN Lu,LIU Jing-jing,

ZHANG Wei,ZHU Xiu-lin

Journal of Functional Polymers,2016,29（1）：20-28.

The chiral solvent induction strategy can avoid the use of expensive chiral reagents and expand the chiral substance synthesized,which covered the organic small molecules,oligomers and polymers systems.

Papers

Preparation of GeIatin-Epoxy PoIy（ether amine）CrossIinked Membrane and Its Adsorption Behavior for Heavy MetaIIons

ZHANG Sai,SHI Zi-xing,YIN Jie

Journal of Functional Polymers,2016,29（1）：29-35.

Gelatin was chemically crosslinked by ePEA,which could improve the stability of the gelatin membrane swelling in water.And the gelatin/ePEA crosslinked membrane exhibited a good adsorption ability to Cu2＋,Pb2＋and Cd2＋in water.

ThermaI AnaIysis of PoIyIactide-Monomethoxy PoIyethyIene GIycoI BIends by ModuIated DifferentiaI Scanning CaIorimetry

XU Li,LI Ruo-yun,ZHENG Na,

PU Qun,HU Ji-jiang,FENG Lian-fang

Journal of Functional Polymers,2016,29（1）：36-42.

The overlap transitions of recrystallization and melting of the PLA-MPEG blends were discriminated effectually by MDSC.With the increase of modulation period,the peak shape of melting in the reversible curves transformed from wide multiple peaks to a separating single peak,and the fraction of melting on reversible curves reached 95.2%.

Fabrication of PoIyaniIine NanoparticIes via the co-AssembIy of MacromoIecuIes

HUANG Jing,SUN Jun,LUO Jing,

LIU Xiao-ya

Journal of Functional Polymers,2016,29（1）：43-50.

Driven by the hydrophobic effect and the electrostatic interaction,P（AA-co-VP-co-St）and PANI could be co-assembled into uniformly dispersed PANI nanoparticles.

Preparation and EmuIsifying Performance of Core Cross-Linked AmphiphiIic PoIymeric CoIIoidaI ParticIes

HU Qiong,ZHU Ye,WEI Wei,

YI Cheng-lin,GU Yao,LIU Xiao-ya

Journal of Functional Polymers,2016,29（1）：51-60.

The amphiphilic polymeric colloidal particles（PDVB@PAS）with crosslinked poly（divinyl benzene）as core and poly（acrylic acid-r-styrene）as outer copolymer chains were used as particulate emulsifiers.The size,amphipathicity,and emulsibility of the colloidal particles could be regulated effectively by varying the chemical constitution of the outer macromolecular chains.

Synthesis of PoIy methacryIic acid Nano-HydrogeIs in Water

GU Wen-juan,LU Ya-ming,

ZHANG You-wei,ZHAO Jiong-xin

Journal of Functional Polymers,2016,29（1）：61-67.

Driven by the hydrophobic interactions between two surfactants and the hydrogen bonding interactions between the surfactant and monomers,methacrylic acid （MAA）monomers are selectively polymerized on the surface of poly（methyl methacrylate）（PMMA）nanolatex seed formed in-situ,thus realizing the“green”synthesis of PMAA nano-hydrogels in water.

Preparation and Adsorption Property of Quercetin Magnetic MoIecuIarIy Imprinted PoIymers

RUAN Yong-xin,MA Ying-xia,

WANG Ru-juan,XING Dan,

DU Xue-yan,ZHANG Wen-juan

Journal of Functional Polymers,2016,29（1）：68-74.

Quercetin magnetic molecularly imprinted polymers（Qu-MMIPs）with excellent magnetic responsiveness were prepared via one-pot method.Genistein（Ge）,the structural analogue of quercetin,was gleaned as competitor to study the adsorption selectivity of Qu-MMIPs.The great discrimination of imprinted factors（α）between the selected substrates revealed favorable specific recognizing properties of the as-synthesized polymers for Qu.

A Modified PBT for Fused Deposition ModeIing in 3D Printing

CAO Shi-qing,SUN Li,XUE Wei-lan,

ZENG Zuo-xiang,ZHU Wan-yu

Journal of Functional Polymers,2016,29（1）：75-79.

Modified poly（butylene terephalate）（poly（butylene terephalate-co-isophthalate-cosebacate）（PBTIS））were prepared for fused deposition modeling in 3D printing by direct esterification and subsequent polycondensation using terephthalic acid （PTA）,isophthalic acid（PIA）,sebacic acid（SA）and 1,4-butanediol（BDO）.The samples of PBTIS were changed into filaments by a desktop drawing machine and printed using a 3D printer,which could be 3D printed fluently.

Syhthesis and Properties of Side-Chain Liquid-CrystaIIine PoIysiIoxanes Exhibiting ChoIesteric PIateIet Texture

LI Ying

Journal of Functional Polymers,2016,29（1）：80-84.

Side-chain liquid-crystalline polysiloxanes（SCLCP）were synthesized through hydrosilylation,grafting（trans,trans）-4-propyl-4＇-propenyl-bicyclohexane.SCLCP exhibits cholesteric platelet texture.

Synthesis of PoIy（amino acid-based ionic Iiquid）s and Their Performance for CO2Absorption

YE Hai-feng,GUO Hui,LI Cao,

CHEN Xue-qin,JIANG Bing-bing

Journal of Functional Polymers,2016,29（1）：85-90.

A solid sorbent material of poly（amino acid-based ionic liquid）（P［METAC］［Gly］）was obtained,which presented a CO2absorption and demonstrated a recycling ability by temperature swing.

Preparation and Characterization of TheophyIIine MoIecuIarIy Imprinted PoIyimide Nanofiber Membrane

LÜJian-feng,XU Zhen-liang,

MA Xiao-hua

Journal of Functional Polymers,2016,29（1）：91-97.

Theophylline（THO）molecularly imprinted polyimide nanofiber composite membrane（PIMIM）was synthesized by surface thermal crosslinking reaction on PIM,which was pre-coated by polymethacrylic acid（PMAA）.PIMIM showed good performance with a high static adsorption binding capacity of for THO,and an acceptable selective separation factor of THO and theobromine（TB）.

PVA-SiO2Composites Modified Cotton Fiber and Its OiI-Absorption Properties

WANG Jin-tao,LI Jia-li,

ZHANG Ye-song,WANG Guo-rong,

LIU Qi,ZHANG Shou-cun

Journal of Functional Polymers,2016,29（1）：98-102.

PVA-SiO2coated cotton fiber for oil absorption exhibits excellent wetting durability and reusability.

Synthesis and PhotoIuminescence Properties of Iridium-FIuorene Main-Chain CopoIymers

CAI Li-mei,LUO Cai-ping,

ZENG Hui-juan,LI Dong-dong,

LIN Mei-juan

Journal of Functional Polymers,2016,29（1）：103-108.

The cyclometalated iridium complex based on 2-（4-bromophenyl）-benzimidazole and acetylacetonate was prepared and then introduced into polyfluorene subject to obtain the main-chain copolymers.Iridium complex emitted green-light and the copolymers exhibited blue emission of PFO subject and green emission of iridium complex.The green light intensity was enhanced with the increasing of iridium complex content.

Review

Progress in RadicaI TechnoIogy for α-oIefins HomopoIymerization or CopoIymerization with FunctionaI Monomers

SHEN Xian-rong,FU Zhi-sheng,LIN Ying,GAO Jian-gang

Journal of Functional Polymers,2016,29（1）：109-114.

Research on the synthesis of high performance polyolefins is of great significance to both academic study and industrial applications.Using radical technology in non polar monomer homopolymerization or copolymerization with functional monomers was summarized.

特约综述